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Nitroxide-mediated
radical polymerization is a
method of
radical polymerization that
makes use of an
nitroxide initiator to
generate polymers with well...
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general structure R2N–O•. It is
commonly known as a
nitroxyl radical or a
nitroxide,
however IUPAC discourages the use of
these terms, as they erroneously...
- a short-lived
intermediate in solution. Its
conjugate base, NO−, the
nitroxide anion, is the
reduced form of
nitric oxide (NO) and is
isoelectronic with...
- used as a
nitroxide spin label. MTSL is bifunctional,
consisting of the
nitroxide and the
thiosulfonate ester functional groups. The
nitroxide label is...
- N-oxoammonium species.
Nitroxides may also be used in
catalytic amounts in the
presence of a
stoichiometric amount of a
terminal oxidant.
Nitroxide radical species...
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which are
stabilized by
steric and/or
resonance effects. For example, the
nitroxide radical in (2,2,6,6-tetramethylpiperidin-1-yl)oxyl (TEMPO), the most common...
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September 2018. Damiani, E.; Greci, L.; Parsons, R.; Knowland, J. (1999). "
Nitroxide radicals protect DNA from
damage when
illuminated in
vitro in the presence...
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polymerization methods, such as atom-transfer radical-polymerization (ATRP),
nitroxide mediated radical polymerization (NMP), or
reversible addition−fragmentation...
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dehydrogenation of alcohols.
Oxoammonium salts are diamagnetic,
whereas the
nitroxide has a
doublet ground state. A
prominent N-oxoammonium salt is prepared...
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Synthesis Chain polymerization Radical polymerization RDRP] ATRP RAFT
Nitroxide-mediated
radical polymerization Step
polymerization Condensation polymerization...
