-
deprotonation of the α-carbon, the pKa of
which is
typically around 17.
Nitronates are
formed as
intermediates in the
Henry reaction, H****–Bender oxidation...
- The salt is
protonated forming the
nitronic acid 2 (in some
cases these nitronates have been isolated) and once more to the
iminium ion 3. This intermediate...
-
Nitrosating a
nitronate gives a
nitrolic acid.
Nitronates are also key
intermediates in the Nef reaction: when
exposed to
acids or oxidants, a
nitronate hydrolyzes...
-
Nitronate monooxygenase (EC 1.13.12.16, NMO) is an
enzyme with
systematic name
nitronate:oxygen 2-oxidoreductase (nitrite-forming). This
enzyme catalyses...
- Jack
Melton (1977). "Conversion of
Nitro to
Carbonyl by
Ozonolysis of
Nitronates: 2,5-Heptanedione".
Organic Syntheses. 56: 36. doi:10.15227/orgsyn.056...
- Melton, J. (1988). "Conversion of
Nitro to
Carbonyl by
Ozonolysis of
Nitronates: 2,5-Heptanedione".
Organic Syntheses;
Collected Volumes, vol. 6, p. 648...
- TMS-protected
nitronate with N-PMB or N-PMP
imines catalysed by Sc(OTf)3. The
authors first attempted the nitro-Mannich
reaction using lithium-
nitronates, however...
- also
called propionate-3-
nitronate oxidase. It
employs one cofactor, FMN.
Porter DJ,
Bright HJ (1987). "Propionate-3-
nitronate oxidase from Penicillium...
-
using nitroethane. The
reaction proceeds via the
intermediacy of the
nitronate anion. Most
nitrolic acids are
laboratory curiosities. One
exception is...
-
Sukhorukov (2023). "Reductive
Denitrogenation of Six-membered
Cyclic Nitronates to
Densely Substituted Dihydrofurans with Raney® Nickel/AcOH System"....
