-
deprotonation of the α-carbon, the pKa of
which is
typically around 17.
Nitronates are
formed as
intermediates in the
Henry reaction, H****–Bender oxidation...
-
Nitronate monooxygenase (EC 1.13.12.16, NMO) is an
enzyme with
systematic name
nitronate:oxygen 2-oxidoreductase (nitrite-forming). This
enzyme catalyses...
- The salt is
protonated forming the
nitronic acid 2 (in some
cases these nitronates have been isolated) and once more to the
iminium ion 3. This intermediate...
-
Nitrosating a
nitronate gives a
nitrolic acid.
Nitronates are also key
intermediates in the Nef reaction: when
exposed to
acids or oxidants, a
nitronate hydrolyzes...
- Melton, J. (1988). "Conversion of
Nitro to
Carbonyl by
Ozonolysis of
Nitronates: 2,5-Heptanedione".
Organic Syntheses;
Collected Volumes, vol. 6, p. 648...
- Jack
Melton (1977). "Conversion of
Nitro to
Carbonyl by
Ozonolysis of
Nitronates: 2,5-Heptanedione".
Organic Syntheses. 56: 36. doi:10.15227/orgsyn.056...
-
nitroalkanes to give
nitronate alkoxides that
yield mainly syn-nitro
alcohols once protonated, and
finally generation of
nitronate anions in
which one...
-
Sukhorukov (2023). "Reductive
Denitrogenation of Six-membered
Cyclic Nitronates to
Densely Substituted Dihydrofurans with Raney® Nickel/AcOH System"....
- with
neighboring conjugating groups (e.g.,
allylic anions, enolates,
nitronates, etc.) are
generally planar rather than pyramidized. Likewise, delocalized...
-
Conversion of
Nitro to
Carbonyl Group by
Dimethyldioxirane (DMD)
Oxidation of
Nitronate Anions". Synlett. 1998 (12): 1335–1336. doi:10.1055/s-1998-1947....
