- form β-nitro alcohols. This type of
reaction is also
referred to as a
nitroaldol reaction (nitroalkane, aldehyde, and alcohol). It is
nearly analogous...
- base catalysis,
nitromethane adds to
aldehydes in 1,2-addition in the
nitroaldol reaction. Some
important derivatives include the
pesticides chloropicrin...
- base is
called a nitronate, and
behaves similar to an enolate. In the
nitroaldol reaction, it adds
directly to aldehydes, and, with enones, can
serve as...
- the
presence of a
basic catalyst like n-butylamine. The
reaction is a
nitroaldol reaction, and is a
variant of a
Knoevenagel condensation reaction, which...
- lanthanide-binaphtholate
complex in 1992,
which was used to
catalyse nitroaldol reactions. The
complex was not
characterised but was the
first to perform...
- and the
PolymerSupported TBD (P-TBD):
Three Efficient Catalysts for the
Nitroaldol (Henry)
Reaction and for the
Addition of
Dialkyl Phosphites to Unsaturated...
-
initiates an SN2
reaction to
displace the
benzyl halide.
Unlike in the
nitroaldol reaction,
where the
deprotonated carbon of the
nitroalkyl group is the...
-
through several different routes, the two most
widely known being the
nitroaldol condensation between indole-3-carboxaldehyde and
nitroethane under ammonium...
- di(hydroxymethyl)nitromethane,
which is
derived from
nitromethane by a
nitroaldol reaction.
World production increased from the tens of
tonnes in the late...
- 4.72. Chougnet, Antoinette; Woggon, Wolf-D. (2013). "Enantioselective
Nitroaldol (Henry)
Reaction of p-Nitrobenzaldehyde and
Nitromethane Using a Copper...
