-
Metal nitrido complexes are
coordination compounds and
metal clusters that
contain an atom of
nitrogen bound only to
transition metals.
These compounds...
- the
strongest π
donor known among ligands (the second-strongest is O2−).
Nitrido complexes are
generally made by the
thermal decomposition of
azides or...
-
strongest π
donor known amongst ligands (the second-strongest is O2−).
Nitrido complexes are
generally made by
thermal decomposition of
azides or by deprotonating...
-
emitting diodes was
recognized by the 2014
Nobel Prize in Physics.
Metal nitrido complexes are also common.
Synthesis of
inorganic metal nitrides is challenging...
-
radioactive concerns common to all
uranium chemistry,
production of
uranium nitrido complexes has been
slowed by
harsh reaction conditions and
solubility challenges...
- Cp2Mo2(SH)2S2 NH−2
amido HgNH2Cl N3−
nitride [Ir3N(SO4)6(H2O)3]4−, see
metal nitrido complex CO
carbonyl Fe2(CO)9, see
bridging carbonyl Cl−
chloride Nb2Cl10...
- OsO4 + Me3CNH2 → OsO3(NCMe3) + H2O Similarly, with NH3 one
obtains the
nitrido complex: OsO4 + NH3 + KOH → K[Os(N)O3] + 2 H2O The [Os(N)O3]−
anion is...
- 4-unsaturated
carbonyl compounds.
Azides can be used as
precursors of the
metal nitrido complexes by
being induced to
release N2,
generating a
metal complex in...
- Man, Wai-Lun; Lam,
William W. Y.; Lau, Tai-Chu (2014). "Reactivity of
Nitrido Complexes of Ruthenium(VI), Osmium(VI), and Manganese(V)
Bearing Schiff...
- Bis(triphenylphosphine)iminium
chloride is the
chemical compound with the
formula [((C6H5)3P)2N]Cl,
often abbreviated [(Ph3P)2N]Cl,
where Ph is phenyl...
