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NacNac is a
class of
anionic bidentate ligands. 1,3-****timines are
often referred to as "HNacNac", a
modification of the
abbreviation Hacac used for 1...
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diacetylpyridine and
acetylacetone gives, respectively,
diiminopyridine and
NacNac ligands. R. R.
Schrock (2009). "Recent
Advances in High
Oxidation State...
-
borylenes and carbenes. β-****timinate
ligands (commonly
referred to as
NacNac ligands) are
commonly emplo**** to
stabilize gallylenes.
These ligands have...
- of
molecular hydrides of
calcium are known. One
example is (Ca(μ-H)(thf)(
nacnac))2.
Calcium monohydride Zumdahl,
Steven S. (2009).
Chemical Principles (6th ed...
- β-****timinato ligands, an
example of a
NacNac ligand. It is
anionic and bidentate.
Shown are
tautomers of a
substituted HNacNac ligand precursor, and...
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monoanionic ligand. For example, β-****timinate,
commonly referred to as
Nacnac, is a
useful chelate regarding these complexes. By
tuning the ligand, the...
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giving rise to
Nacac and
Nacnac ligands.
hexafluoroacetylacetone trifluoroacetylacetone Tautomers and
complexation of
Nacnac The "NMR
shift reagent" Eufod...
- cluster.
Related bulky anionic ligands include C5Me5−, (Me3Si)2N−, and
NacNac−.
Silox has a
larger cone
angle than C5Me5− and is a
poorer donor. It is...
-
first monomeric aluminium(I)
compound was
isolated on a β-****timinate
NacNac-type
ligand by
Roesky and
coworkers in 2000. This
initial monomeric aluminium(I)...
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alkyl or aryl) are
often non-innocent. In contrast, [D-CR=CR-CR=D]− such as
NacNac or acac are innocent.
catecholates and
related 1,2-dioxalenes. dithiolenes...