- the
denticity equals one, and the
ligand is said to be
unidentate or
monodentate.
Ligands with more than one
bonded atom are
called multidentate or polydentate...
-
chelate complexes. They tend to be more
stable than
complexes derived from
monodentate ligands. This
enhanced stability,
called the
chelate effect, is usually...
-
chelating ligands for a
metal ion than that of
similar nonchelating (
monodentate)
ligands for the same metal. The
thermodynamic principles underpinning...
-
studies have
revealed a
divergent reaction pathways depending on
whether monodentate or
chelating phosphine ligands are emplo**** in the reaction, and a number...
-
contain at
least one lone pair of electrons. If all the
ligands are
monodentate, then the
number of
donor atoms equals the
number of ligands. For example...
-
structure of
MonoPHOS or the
spiro ring
system of SiPHOS. Notably,
these monodentate ligands can be used in
combination with each
other to
achieve a synergistic...
-
phosphate ligands. The
dihydrogen phosphate ligands are
bound to Al3+ as
monodentate ligands. "Aluminum
Phosphate Monobasic".
American Elements. Retrieved...
-
strongly alkaline solutions. Beryllium(II)
forms few
complexes with
monodentate ligands because the
water molecules in the aquo-ion, [Be(H2O)4]2+ are...
-
Carboxylates exhibit a
variety of
coordination modes, most
common are κ1- (O-
monodentate), κ2 (O,O-bidentate), and bridging.
Carboxylates bind to
single metals...
- The
sulfate ion can act as a
ligand attaching either by one
oxygen (
monodentate) or by two
oxygens as
either a
chelate or a bridge. An
example is the...
