-
process (known as the
Stork enamine synthesis)
constitutes a
selective monoalkylation of a
ketone or aldehyde, a
process that may be
difficult to achieve...
-
proceeds usually at nitrogen. One
challenge is
dialkylation when only
monoalkylation is desired.
RNHOH + R'X → RR'NOH + HX For O-alkylation of hydroxylamines...
- Gérard Cahiez, François Chau,
Bernard Blanchot (1999). "Regioselective
Monoalkylation of
Ketones Via
Their Manganese Enolates: 2-Benzyl-6-Methylcyclohexanone...
-
agents can
react only with one 7-N of guanine.
Limpet attachment and
monoalkylation do not
prevent the
separation of the two DNA
strands of the
double helix...
- ISBN 9780471854722. OCLC 642506595. Stork, G.; Benaim, J. (1977). "
Monoalkylation of α,β-Unsaturated
Ketones via Metalloenamines: 1-butyl-10-methyl-Δ1(9)-2-octalone"...
-
marrow transplantation,
complications from the
therapy can be fatal.
Monoalkylation of DNA
leads to
mispairing of
bases and, if not repaired, can reside...
- Gérard Cahiez, François Chau,
Bernard Blanchot (1999). "Regioselective
Monoalkylation of
Ketones Via
Their Manganese Enolates: 2-Benzyl-6-Methylcyclohexanone...
