Definition of MgBrCl. Meaning of MgBrCl. Synonyms of MgBrCl

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Definition of MgBrCl

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Meaning of MgBrCl from wikipedia

- halogen-magnesium exchange: fast, homogeneous: XC6H4Br + i−PrMgCl·LiCl → XC6H4MgCl·LiCl + i−PrCl + MgBrCl The traditional method for generating the aryl Grignard...
- iron(III) chloride, resulting in ferrocene: 3 C5H5MgBr + FeCl3 → Fe(C5H5)2 + 1/n (C5H5)n + 3 MgBrCl This conversion, although not of practical value, was...
- ethylmagnesium bromide with tin(IV) chloride: SnCl4 + 4 CH3CH2MgBr → (CH3CH2)4Sn + 4 MgBrCl The same reaction can be used to obtain tetra-n-propyltin and...
- PbCl2 + 4 RLi → R4Pb + 4 LiCl + Pb 2 PbCl2 + 4 RMgBr → R4Pb + Pb + 4 MgBrCl 3 PbCl2 + 6 RMgBr → R3Pb-PbR3 + Pb + 6 MgBrCl These reactions produce derivatives...
- tris(4-methoxyphenyl)phosphine: 3 CH3OC6H4MgBr + PCl3 → (CH3OC6H4)3P + 3 MgBrCl 4-Bromoanisole forms the organozinc derivative CH3OC6H4ZnBr. 4-Bromoanisole is compound...
- tetraaryltin compounds can be prepared using Grignard reagents: SnCl 4 + 4 RMgBr → R 4Sn + 4 MgBrCl The mixed halide-alkyls, which are more common and more important...
- by the synthesis of dibutyldivinyltin: Bu2SnCl2 + 2 CH2=CHMgBr → Bu2Sn(CH=CH2)2 + 2 MgBrCl The organotin hydrides are generated by reduction of the mixed...
- Illustrative is preparation of tris(pentafluorophenyl)borane: 3 C6F5MgBr + BCl3 → (C6F5)3B + 3 MgBrCl Other derivatives include LiB(C6F5)4, [CuC6F5]4, and Ni(C6F5)2(dioxane)2...
- reaction of phenylmagnesium bromide and selenium: PhMgBr + Se → PhSeMgBr PhSeMgBr + HCl → PhSeH + MgBrCl Since benzeneselenol does not have a long shelf life...
- acid workup: (C2H5O)2P(O)H + 3 C6H5MgBr → (C6H5)2P(O)MgBr + C2H5OMgBr (C6H5)2P(O)MgBr + HCl → (C6H5)2P(O)H + MgBrCl Alternatively, it may be prepared by...