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Methylphosphine is the
simplest organophosphorus compound with the
formula CH3PH2,
often written MePH2. It is a
malodorous gas that
condenses to a colorless...
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methyl sulfides (H−CH2SR),
thioacetals (H−CH(SR)2, e.g. dithiane),
methylphosphines (H−CH2PR2), furans,
thiophenes and
ferrocene (Fe(H−C5H4)(C5H5)). In...
- Phosphorus(III)
bromide difluoride PBrF2 −16.1 −133.8 149 15597-40-7
Methylphosphine CH3PH2 −16 48 593-54-4
Fluorine perchlorate FOClO3 −16 −167.3 118.5...
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ether 838
Dimethyl sulfide 839 Iron
pentacarbonyl 845
Ammonia 854
Methylphosphine 854
Hydrazine 856
Diethyl sulfide 858 1,6-Dicarba-closo-hexaborane(6)...
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mercaptan (roasted coffee)
Benzyl mercaptan (l**** or garlic-like)
Methylphosphine and
dimethylphosphine (garlic-metallic, two of the most
potent odorants...
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prepared by
alkylation of phosphine.
Simple alkyl derivatives such as
methylphosphine (CH3PH2) are
prepared by
alkylation of
alkali metal derivatives MPH2...
- groups, an
early example being the
internal oxidative addition of
methylphosphine ligands.
Metallacycle formation interferes with
intermolecular C-H...
- is
obtained by
treating Na2[Fe(CO)4] and dichlorobis(trimethylsilyl)
methylphosphine. ArP=PArFe(CO)4 (Ar=2,4,6-tri-tert-butylphenyl)
arises simply by treating...
