Definition of Methyllithium. Meaning of Methyllithium. Synonyms of Methyllithium

- Methyllithium is the simplest organolithium reagent, with the empirical formula LiCH3. This s-block organometallic compound adopts an oligomeric structure...
- (Trimethylsilyl)methyllithium is classified both as an organolithium compound and an organosilicon compound. It has the empirical formula LiCH2Si(CH3)3...
- the reaction of an aziridine carrying a methylene bromide group with methyllithium: In this reaction one equivalent of acetylene is lost. Ferrier rearrangement...
- structures. For example, methyllithium, ethyllithium and tert-butyllithium all exist in the tetramer [RLi]4. Methyllithium exists as tetramers in a cubane-type...
- however. Tert-butyllithium deprotonates DCM: H2CCl2 + RLi → HCCl2Li + RH Methyllithium reacts with methylene chloride to give chlorocarbene:[citation needed]...
- consisted of treating cyclopentadiene with methyllithium in dimethyl ether and then with dichloromethane and methyllithium in diethyl ether at −45 °C. It can...
- deprotonated in solution, but the conjugate base is known in forms such as methyllithium. A variety of positive ions derived from methane have been observed...
- addition reaction, and not aromatic substitution. Thus for example methyllithium adds to phosphorus in phosphorine whereas it adds to the 2-position...
- prepared by the salt metathesis reaction of methylmagnesium chloride or methyllithium with titanocene dichloride: Cp2TiCl2 + 2 CH3MgCl → Cp2Ti(CH3)2 + 2 MgCl2...
- silyl enol ethers, can also be generated from silyl enol ethers using methyllithium. The reaction occurs via nucleophilic substitution at the silicon of...