-
compounds and a
variety of N‐tosylhydrazones
catalysed by Co(II)–porphyrin
metalloradicals leading to the
formation of ketenes,
which subsequently react with...
- Puschmann, F.F.; Grützmacher, H.; de Bruin, B. (2010). "Rhodium(0)
Metalloradicals in
Binuclear C−H Activation".
Journal of the
American Chemical Society...
- "Effect of
Steric Congestion on the
Activity of
Chromium and
Molybdenum Metalloradicals as
Chain Transfer Catalysts during MMA Polymerization". Macromolecules...
- with Acceptor/Acceptor-Substituted
Diazo Reagents via Co(II)-Based
Metalloradical Catalysis".
Chemical Science. 6 (2): 1219–1224. doi:10.1039/C4SC02610A...
-
possibly another driving force for this reaction. In addition, the
metalloradical has also been
proven to have the
ability to
cleave the C–C
single bond...
- Cobalt(III)-Carbene Radicals: Key
Intermediates in Cobalt(II)-Based
Metalloradical Cyclopropanation".
Journal of the
American Chemical Society. 133 (22):...
-
Homolytic cleavage,
usually via light, but
sometimes heat,
gives the Mn(0)
metalloradical,
which can
react with
itself to
reform Mn2(CO)10, or
combine with other...
- [Ta(CNDipp)7][Ta(CNDipp)6], a
formal disproportionation product of the 17-electron Ta0
metalloradical Ta(CNDipp)6". Acta
Crystallographica Section C:
Structural Chemistry...
