- In
organometallic chemistry, a
metallacycle is a
derivative of a
carbocyclic compound wherein a
metal has
replaced at
least one
carbon center; this is...
-
Supramolecular metallocycles are
macrocyclic aggregates with
metal ions in the ring,
often formed from
angular and
linear modules.
Common metallocycle shapes...
- been
demonstrated with
thioesters capable of
forming the six-membered
metallocycle,
boronic acids, and stannanes. The first-generation
approach to cross...
- instance,
certain Pt(II)
complexes undergo γ- and δ-elimination to give
metallocycles. More recently, γ-silyl
elimination of a
silylcyclobutyl tosylate has...
- reactions:
those in
which the
metal is
incorporated into the
cycle (a
metallocycle), and
those in
which the
metal is
external to the cycle.
These can be...
- by
oxidative addition of a C-H bond. The
resulting five-coordinated
metallocycle is
stabilized by an
agostic interaction. The C-C bond
formation is the...
- and oxazolines. NHC-based
catalysts featuring a
bulky seven-membered
metallocycle on
iridium have been
applied to the
catalytic hydrogenation of unfunctionalized...
-
cation [W(PMe3)4(η2-CHPMe2)H]+ with the
corresponding halide anion. The
metallocycle was
determined to be an
alkylidene based on the W-C bond
length of the...
- PMID 11710218. Thorn, D.L.; Hoffmann, R. (1979). "Delocalization in
Metallocycles". Nouv. J. Chim. 3 (1): 39. Elliott, G.P.; Roper, W.R.; Waters, J.M...
