- The
chalcogenide metallates are
known as oxometallates, thiometallates,
selenometallates and tellurometallates; the
cyanide metallates are
known as cyanometallates...
- that n-butyllithium
normally adopts. BuLi/TMEDA is able to
metallate or even
doubly metallate many
substrates including benzene, furan, thiophene, N-alkylpyrroles...
-
boronic ester to give an ate complex. The ate
complex undergoes a 1,2-
metallate rearrangement to give the
homologated product,
which is then
further oxidised...
- Many
metallated paramagnetic texaphyrin species exhibit triplet-state
lifetimes in the
nanosecond range.
These results are
mirrored by
metallated PCs....
-
Relativistic coupled cluster calculations for the di-, tetra- and
hexafluoro metallates of Cu, Ag, Au, and
element 111". J. Chem. Phys. 109 (10): 3935–43. Bibcode:1998JChPh...
-
benzothiazole sulfone (1) with
lithium diisopropylamide (LDA)
gives a
metallated benzothiazolyl sulfone,
which reacts quickly with
aldehydes (or ketones)...
- Volumes, vol. 3, p. 185. Jarowicki, K.; Kocienski, P. J.; Qun, L. "1,2-
Metallate Rearrangement: (Z)-4-(2-Propenyl)-3-Octen-1-ol".
Organic Syntheses. 79:...
- C6H5HgCCl3 → CCl2 + C6H5HgCl It
remains uncertain which (if any) of such
metallated reagents form
truly free carbenes,
instead of a
reactive metal-carbene...
-
necessary for the
synthesis of many
organic molecules. In synthesis,
metallated reagents are
typically involved in
nucleophilic substitution, single-electron-transfer...
-
Tetrachloroferrate is the
polyatomic ion
having chemical formula FeCl−4. The
metallate can be
formed when
ferric chloride (FeCl3)
abstracts a
chloride ion from...
