-
Metallate or
metalate is the name
given to any
complex anion containing a
metal ligated to
several atoms or
small groups. Look up
metallate in Wiktionary...
-
necessary for the
synthesis of many
organic molecules. In synthesis,
metallated reagents are
typically involved in
nucleophilic substitution, single-electron-transfer...
- Many
metallated paramagnetic texaphyrin species exhibit triplet-state
lifetimes in the
nanosecond range.
These results are
mirrored by
metallated PCs....
-
boronic ester to give an ate complex. The ate
complex undergoes a 1,2-
metallate rearrangement to give the
homologated product,
which is then
further oxidised...
- that n-butyllithium
normally adopts. BuLi/TMEDA is able to
metallate or even
doubly metallate many
substrates including benzene, furan, thiophene, N-alkylpyrroles...
- in the molecule. Aza
enolates (also
known as
imine anions, enamides,
metallated Schiff bases, and metalloenamines) are
nitrogen analogous to enolates...
- on the
scope and
stereochemistry of the
Julia olefination with alpha-
metallated sulphone reagents emphasised the
value of this
method in
organic chemistry...
- triphenylphosphine. The
bromide also
forms a
Grignard reagent.
These metallated phosphines are
versatile reagents. BrC6H4PPh2 + Mg → BrMgC6H4PPh2 2 BrMgC6H4PPh2...
- palladium(II), iridium(III) and ruthenium(II) from chloro-bridged ortho-
metallated metal compounds and [(OC)3Ru(Cl)(μ-Cl)]2".
Journal of
Organometallic Chemistry...
- the
stereoselective generation of
alkenes via
thermal decomposition of
metallated tosylhydrazones due to the
indiscriminate 1,2-rearrangement of the carbene...
