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Metallate or
metalate is the name
given to any
complex anion containing a
metal ligated to two or more
atoms and/or
groups of atoms. Look up metallate...
-
necessary for the
synthesis of many
organic molecules. In synthesis,
metallated reagents are
typically involved in
nucleophilic substitution, single-electron-transfer...
- Many
metallated paramagnetic texaphyrin species exhibit triplet-state
lifetimes in the
nanosecond range.
These results are
mirrored by
metallated PCs....
- that n-butyllithium
normally adopts. BuLi/TMEDA is able to
metallate or even
doubly metallate many
substrates including benzene, furan, thiophene, N-alkylpyrroles...
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boronic ester to give an ate complex. The ate
complex undergoes a 1,2-
metallate rearrangement to give the
homologated product,
which is then
further oxidised...
- in the molecule. Aza
enolates (also
known as
imine anions, enamides,
metallated Schiff bases, and metalloenamines) are
nitrogen analogous to enolates...
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benzothiazole sulfone (1) with
lithium diisopropylamide (LDA)
gives a
metallated benzothiazolyl sulfone,
which reacts quickly with
aldehydes (or ketones)...
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Tetrachloroferrate is the
polyatomic ion
having chemical formula FeCl−4. The
metallate can be
formed when
ferric chloride (FeCl3)
abstracts a
chloride ion from...
- C6H5HgCCl3 → CCl2 + C6H5HgCl It
remains uncertain which (if any) of such
metallated reagents form
truly free carbenes,
instead of a
reactive metal-carbene...
- reactivity.
Benzene can be
metallated by
alkylsodium compounds resulting in phenylsodium. The
phenylsodium is then able to
metallate other aromatic compounds...
