-
Metallate or
metalate is the name
given to any
complex anion containing a
metal ligated to
several atoms or
small groups. Look up
metallate in Wiktionary...
-
necessary for the
synthesis of many
organic molecules. In synthesis,
metallated reagents are
typically involved in
nucleophilic substitution, single-electron-transfer...
- Many
metallated paramagnetic texaphyrin species exhibit triplet-state
lifetimes in the
nanosecond range.
These results are
mirrored by
metallated PCs....
- that n-butyllithium
normally adopts. BuLi/TMEDA is able to
metallate or even
doubly metallate many
substrates including benzene, furan, thiophene, N-alkylpyrroles...
- Volumes, vol. 3, p. 185. Jarowicki, K.; Kocienski, P. J.; Qun, L. "1,2-
Metallate Rearrangement: (Z)-4-(2-Propenyl)-3-Octen-1-ol".
Organic Syntheses. 79:...
- in the molecule. Aza
enolates (also
known as
imine anions, enamides,
metallated Schiff bases, and metalloenamines) are
nitrogen analogous to enolates...
- on the
scope and
stereochemistry of the
Julia olefination with alpha-
metallated sulphone reagents emphasised the
value of this
method in
organic chemistry...
- Dipalladium(III)
complexes derived from ortho-
metallated triphenylphosphine (Ph
groups omitted for clarity)....
-
alkylation reaction. In 1976,
Meyers reported the
first alkylation reaction of
metallated azaenolates of
hydrazones with an
acyclic amino acid-based auxiliary....
- (link)
Krzysztof Jarowicki,
Philip J. Kocienski, Liu Qun (2002). "1,2-
Metallate Rearrangement: (Z)-4-(2-Propenyl)-3-Octen-1-Ol".
Organic Syntheses. 79:...
