Definition of Metallacyclobutane. Meaning of Metallacyclobutane. Synonyms of Metallacyclobutane

- for the M(η2-alkene) center is the metallacyclopropane. The parent metallacyclobutane has the formula LnM(CH2)3 where L is a ligand attached to M. A stable...
- bond to a transition metal alkylidene to form a metallacyclobutane intermediate. The metallacyclobutane produced can then cycloeliminate to give either...
- macroheterocycles. These reactions are metal-catalyzed and proceed through a metallacyclobutane intermediate. It was first published by Dider Villemin in 1980 describing...
- of a transition metal into one of the three C-C bonds leading to a metallacyclobutane intermediate. Substituents on the cyclopropane affect the course of...
- alkylidene complex, followed by a [2+2] type cycloaddition to form the metallacyclobutane intermediate that cycloreverts to form a new alkylidene species. Commercially...
- of the complex strongly encourage the binding of olefins to form metallacyclobutane during catalysis, further validating the potential for highly efficient...
- cycloalkylhydridorhodium complexes to rhodacycloalkanes. Synthesis of metallacyclobutanes, including one with a tertiary metal-carbon bond, by nucleophilic...
- step takes place when this center reacts with the alkene group to a metallacyclobutane 4.5 as in a regular olefin metathesis reaction. The butadiene group...
- alkylplatinum and alkyl–gold complexes and of skeletal rearrangements of metallacyclobutane complexes, often called the Puddephatt rearrangement. Coordinatively...
- cycloalkylhydridorhodium complexes to rhodacycloalkanes. Synthesis of metallacyclobutanes, including one with a tertiary metal-carbon bond, by nucleophilic...