- In
organometallic chemistry, a
metallacycle is a
derivative of a
carbocyclic compound wherein a
metal has
replaced at
least one
carbon center; this is...
-
Selective Trimerization of
Ethylene Affording 1-Hexene: New
Evidence of a
Metallacycle Mechanism".
Journal of the
American Chemical Society. 131 (15): 5370–5371...
-
Organorhodium chemistry is the
chemistry of
organometallic compounds containing a rhodium-carbon
chemical bond, and the
study of
rhodium and
rhodium compounds...
-
transalkylation mechanism (ruled out): In 1971
Chauvin proposed a four-membered
metallacycle intermediate to
explain the
statistical distribution of
products found...
-
structure (amides can also ****ume this role).
Uranium and
thorium both form
metallacycles with a
diverse chemistry.
These complexes are very
labile so trimethylsilyl...
-
Selective Trimerization of
Ethylene Affording 1-Hexene: New
Evidence of a
Metallacycle Mechanism".
Journal of the
American Chemical Society. 131 (15): 5370–5371...
- [Cr2(CH2SiMe3)6]2- and Its
Conversion to the
Unusual "Windowpane" Bis(
metallacycle)
Complex [Cr(κ2C,C-CH2SiMe2CH2)2]2-". Organometallics. 13: 1646. doi:10...
-
oxidative coupling of an
alkyne and an
azide to the
ruthenium containing metallacycle (Ruthenacycle). The new C-N bond is
formed between the more electronegative...
- Ghosh, Kaushik; Pattanayak, Sujoy, and Chakravorty, Animesh(1998), "
Metallacycle Expansion by
Alkyne Insetion.
Chemistry of a New
Family of Ruthenium...
-
interact strongly enough with
copper species to form a
novel type of
metallacycle. Gilbert, John C.; Hou, Duen-Ren (2003). "Competitive Intermolecular...
