- single-electron-transfer
mechanism of the type
shown below.
Magnesium similarly metalates organohalides to give
Grignard reagents. Frankland, E. (1849). "Ueber...
-
preparation of a
series of
strong photoreducing agents: Fac-tris-ortho-
metalated complexes of iridium(III) with
substituted 2-phenylpyridines". Inorganic...
- tris(2-phenylpyridine)iridium. The
degree and
regiochemistry of
fluorination of
metalated 2-phenylpyridine
ligands in platinum(II)
complexes significantly modifies...
-
quaternary ammonium salt is
involved or the aza-Wittig
reaction if an alpha-
metalated tertiary amine is involved; if Y is oxygen, then it is
called a 2,3-Wittig...
-
Other supernucleophilic metal centers include low
oxidation state carbonyl metalate anions (e.g., CpFe(CO)2–). The
following table shows the nucleophilicity...
- base with an
electrophile such as
iodomethane gives N-methylpyrrole. N-
Metalated pyrrole can
react with
electrophiles at the N or C positions, depending...
- 15.
Unsaturated acyl
derivatives of silicon, germanium, and tin from
metalated enol ethers". J. Am. Chem. Soc. 102 (5): 1577–1583. doi:10.1021/ja00525a019...
- ISBN 978-0-471-26418-7. Yang, Xun; Fleming,
Fraser F. (2017). "C- and N-
Metalated Nitriles: The
Relationship between Structure and Selectivity". Accounts...
- pH it
converts to
sodium decavanadate. It is also
precursor to
exotic metalates such as [γ-PV2W10O40]5-, [α-PVW11O40]4-, and [β-PV2W10O40]5-.
Sodium metavanadate...
- t-Butyllithium and s-butyllithium are more basic. n-BuLi can
deprotonate (that is,
metalate) many
types of C−H bonds,
especially where the
conjugate base is stabilized...
