Definition of Metalate. Meaning of Metalate. Synonyms of Metalate

- Metallate or metalate is the name given to any complex anion containing a metal ligated to several atoms or small groups. Look up metallate in Wiktionary...
- Other supernucleophilic metal centers include low oxidation state carbonyl metalate anions (e.g., CpFe(CO)2–). The following table shows the nucleophilicity...
- t-Butyllithium and s-butyllithium are more basic. n-BuLi can deprotonate (that is, metalate) many types of C−H bonds, especially where the conjugate base is stabilized...
- pH it converts to sodium decavanadate. It is also precursor to exotic metalates such as [γ-PV2W10O40]5-, [α-PVW11O40]4-, and [β-PV2W10O40]5-. Sodium metavanadate...
- single-electron-transfer mechanism of the type shown below. Magnesium similarly metalates organohalides to give Grignard reagents. Frankland, E. (1849). "Ueber...
- because porphyrins and related macrocyclic ligands are extremely slow to metalate, despite favorable thermodynamics. These low rates are attributed to the...
- agent with the empirical formula C6H5Li. It is most commonly used as a metalating agent in organic syntheses and a substitute for Grignard reagents for...
- The higher alkali metals are known to metalate even some unactivated hydrocarbons and are known to self-metalate: 2 NaC2H5 → C2H4Na2 + C2H6 In the ****lyn...
- or iodides: i-PrMgCl + ArCl → i-PrCl + ArMgCl Magnesium ate complexes metalate aryl halides: ArBr + Li[MgBu3] → ArMgBu2 + BuBr Zinc–halogen exchange Zinc–halogen...
- metalation is an important class of metalation reactions. Metalated sulfones, acyl groups and α-metalated amides are important intermediates in chemistry synthesis...