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Metallate or
metalate is the name
given to any
complex anion containing a
metal ligated to two or more
atoms and/or
groups of atoms. Look up metallate...
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Other supernucleophilic metal centers include low
oxidation state carbonyl metalate anions (e.g., CpFe(CO)2ā). The
following table shows the nucleophilicity...
- single-electron-transfer
mechanism of the type
shown below.
Magnesium similarly metalates organohalides to give
Grignard reagents. Frankland, E. (1849). "Ueber...
- Na3PO4 Na5P3O10 Na4P2O7 Na2H2P2O7 Na3AsO3 Na3AsO4 Na2HAsO4 NaH2AsO4 NaSbO3
Metalates NaAlH4 NaAlO2 Na3AlF6 NaAl(SO4)2 NaAuCl4 Na2TiF6 NaBiO3 NaCoO2 NaMnO4...
- t-Butyllithium and s-butyllithium are more basic. n-BuLi can
deprotonate (that is,
metalate) many
types of CāH bonds,
especially where the
conjugate base is stabilized...
- Na3PO4 Na5P3O10 Na4P2O7 Na2H2P2O7 Na3AsO3 Na3AsO4 Na2HAsO4 NaH2AsO4 NaSbO3
Metalates NaAlH4 NaAlO2 Na3AlF6 NaAl(SO4)2 NaAuCl4 Na2TiF6 NaBiO3 NaCoO2 NaMnO4...
- Na3PO4 Na5P3O10 Na4P2O7 Na2H2P2O7 Na3AsO3 Na3AsO4 Na2HAsO4 NaH2AsO4 NaSbO3
Metalates NaAlH4 NaAlO2 Na3AlF6 NaAl(SO4)2 NaAuCl4 Na2TiF6 NaBiO3 NaCoO2 NaMnO4...
- The
higher alkali metals are
known to
metalate even some
unactivated hydrocarbons and are
known to self-
metalate: 2 NaC2H5 ā C2H4Na2 + C2H6 In the ****lyn...
- Na3PO4 Na5P3O10 Na4P2O7 Na2H2P2O7 Na3AsO3 Na3AsO4 Na2HAsO4 NaH2AsO4 NaSbO3
Metalates NaAlH4 NaAlO2 Na3AlF6 NaAl(SO4)2 NaAuCl4 Na2TiF6 NaBiO3 NaCoO2 NaMnO4...
- Na3PO4 Na5P3O10 Na4P2O7 Na2H2P2O7 Na3AsO3 Na3AsO4 Na2HAsO4 NaH2AsO4 NaSbO3
Metalates NaAlH4 NaAlO2 Na3AlF6 NaAl(SO4)2 NaAuCl4 Na2TiF6 NaBiO3 NaCoO2 NaMnO4...
