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Manganocene or bis(cyclopentadienyl)manganese(II) is an
organomanganese compound with the
formula [Mn(C5H5)2]n. It is a
thermochromic solid that degrades...
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featuring Mn(I).
Consistent with
other aspects of Mn(II) chemistry,
manganocene (Mn(C5H5)2) is high-spin. In contrast, its
neighboring metal, iron, forms...
- the
synthesis of a
variety of
organomanganese compounds. For example,
manganocene is
prepared by
reaction of MnCl2 with a
solution of
sodium cyclopentadienide...
- also be used to
prepare ferrocene from some
other metallocenes, such as
manganocene: FeCl2 + Mn(C5H5)2 → MnCl2 + Fe(C5H5)2
Ferrocene is an air-stable...
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structures where the
aromatic rings are not parallel, such as
found in
manganocene or
titanocene dichloride (Cp2TiCl2). Some
metallocene complexes of actinides...
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waste sodium hydroxide selectively dissolves in an
aqueous ethanol wash.
Manganocene ammonolyzes at 700 °C to give Mn3N2.
Manganese azides decompose when...
- [Ni(η5-C5H5)2] ruthenocene, [Ru(η5-C5H5)2] osmocene, [Os(η5-C5H5)2]
manganocene, [Mn(η5-C5H5)2] rhenocene, [Re(η5-C5H5)2].
Examples of
compounds that...