- δ-lactone = 6-membered, etc.
Macrocyclic lactones are
known as
macrolactones. Look up
macrolactone in Wiktionary, the free dictionary. The
other suffix used...
- that
underwent transannular 5-exo-dig cyclization. The ansa-bridging
macrolactone was
constructed following the
first Sonogashira coupling,
using the Shiina...
- to form alcohol,
double bonds or
single bonds.
After cyclisation, the
macrolactone core
undergoes further modification by hydroxylation,
methylation and...
-
Habgood GJ,
DiPietro LV, et al. (November 2004). "Structurally
simplified macrolactone analogues of
halichondrin B".
Bioorganic &
Medicinal Chemistry Letters...
-
carbonyl center,
providing a
tetrahedral intermediate that
yields the
macrolactone product. One of the
first examples of this
protocol was
applied to the...
-
There are
various subclasses of
polyketides including: aromatics,
macrolactones/macrolides,
decalin ring containing, polyether, and polyenes. Polyketide...
-
Erythromycin 12
hydroxylase is
responsible for the C-12
hydroxylation of the
macrolactone ring.
Lambalot RH, Cane DE,
Aparicio JJ, Katz L (February 1995). "Overproduction...
-
separate the diastereomers.
Epothilone B is a 16-membered
polyketide macrolactone with a
methylthiazole group connected to the
macrocycle by an olefinic...
-
Streptomyces ssp. Avermectin, from
Streptomyces avermitilis. Epothilones,
macrolactones from the soil-dwelling
myxobacterium Sorangium cellulosum. Erythromycin...
-
glycosyltransferase responsible for the
attachment of TDP-D-desosamine to
macrolactones of
varied ring sizes.
Borisova SA, Liu HW (September 2010). "Characterization...
