-
decarboxylations for the
preparation of
terpenoid macrocycles. So,
while Ružička was able to
produce various macrocycles, the
yields were low. This
kinetic problem...
-
displaying significant symmetry (e.g., in the case of
chelating macrocycles).
Macrocycles can
access a
number of
stable conformations, with
preference to...
-
thermodynamically or
kinetically unlikely, such as in the
preparation of
large macrocycles. This pre-organization also
serves purposes such as
minimizing side reactions...
-
Michel (1999). "Gold(I) and Gold(0)
Complexes of Phosphinine-Based
Macrocycles".
Angewandte Chemie International Edition. 38 (21): 3194–3197. doi:10...
-
molecular architecture in
which three macrocycles are
interlocked in such a way that
breaking any
macrocycle allows the
others to dissociate. They are...
- carbohydrates) and
large non-polymeric
molecules such as lipids,
nanogels and
macrocycles.
Synthetic fibers and
experimental materials such as
carbon nanotubes...
-
natural products such as heme.
Pyrroles are
components of more
complex macrocycles,
including the
porphyrinogens and
products derived therefrom, including...
-
interlocked molecular architecture consisting of two or more
interlocked macrocycles, i.e. a
molecule containing two or more
intertwined rings. The interlocked...
- "thread" is held
within the "
macrocycle" by non-covalent interactions, for
example rotaxinations with
cyclodextrin macrocycles involve exploitation of the...
-
hemoglobin and chlorophyll. In
these two molecules, in particular, the
pyrrole macrocycle ring
frames a
metal atom, that
forms a
coordination compound with the...
