- metal–
ligand bond
order can
range from one to three.
Ligands are
viewed as
Lewis bases,
although rare
cases are
known to
involve Lewis acidic "
ligands". Metals...
-
compounds can
serve as
bridging ligands, so the term is
usually restricted to
small ligands such as
pseudohalides or to
ligands that are
specifically designed...
-
response produced.
Selective ligands have a
tendency to bind to very
limited kinds of receptor,
whereas non-selective
ligands bind to
several types of receptors...
- of two
electrons by each of six σ-donor
ligands to the d-orbitals on the metal. In
octahedral complexes,
ligands approach along the x-, y- and z-axes, so...
-
which are
structurally related to the
classical salen ligand,
primarily bis-Schiff bases.
Salen ligands are
notable for
coordinating a wide
range of different...
- (Triphenylphosphine) < CN− < CO Weak
field ligands: H2O, F−, Cl−, OH−
Strong field ligands: CO, CN−, NH3, PPh3
Ligands arranged on the left end of this spectrochemical...
- a
method of
classifying ligands.
Tetradentate ligands are
common in
nature in the form of chlorophyll,
which has a core
ligand called chlorin, and heme...
- The
Trost ligand is a
diphosphine used in the palladium-catalyzed
Trost asymmetric allylic alkylation.
Other C2-symmetric
ligands derived from trans-1...
-
spectator ligand is a
ligand that does not parti****te in
chemical reactions of the complex. Instead,
spectator ligands (vs "actor
ligands")
occupy coordination...
-
Smart ligands are
affinity ligands selected with pre-defined
equilibrium ( K d {\displaystyle K_{d}} ),
kinetic ( k o f f {\displaystyle k_{off}} , k o...
