-
formula LiN(Si(CH3)3)2. It is
commonly abbreviated as
LiHMDS or
Li(
HMDS) (lithium
hexamethyldisilazide - a
reference to its
conjugate acid
HMDS) and is...
-
Hexamethyldisilazide ([(CH3)3Si]2NM) M =
Li as in
Lithium bis(trimethylsilyl)amide (
LiHMDS) M = Na as in
Sodium bis(trimethylsilyl)amide (Na
HMDS) M = K as in Pot****ium...
-
readily dissociates from
LiHMDS,
leading to the
formation of
LiHMDS dimers that is the more
reactive species. Thus, in the case of
LiHMDS,
TMEDA does not increase...
-
Human Mobile Devices (
HMD),
formally HMD Global, is a
Finnish independent mobile phone manufacturer. The
company is
owned by the
Luxembourgish holding...
-
abbreviated LiTMP or LTMP) is a
chemical compound with the
molecular formula LiC9H18N. It is used as a non-nucleophilic base,
being comparable to
LiHMDS in terms...
-
lithium bis(trimethylsilyl)amide (
LiHMDS) is
prepared using n-butyllithium: [(CH3)3Si]2NH + Bu
Li → [(CH3)3Si]2NLi + BuH
LiHMDS and
other similar derivatives:...
- conditions.
Lithium amide Lithium bis(trimethylsilyl)amide (
LiHMDS)
Lithium tetramethylpiperidide (
LiTMP)
Evans pKa
Table Hamell, Matthew; Levine,
Robert (1950)...
- (tBuONa, tBuOK), lithium,
sodium and pot****ium
hexamethyldisilazide (
LiHMDS, Na
HMDS, KHDMS,
where HDMS = N(SiMe3)2), or
sodium hydride (NaH) are also commonly...
-
compound with the
formula NaN(Si(CH3)3)2. This species,
usually called Na
HMDS (sodium hexamethyldisilazide), is a
strong base used for
deprotonation reactions...
-
yielded mutilin.
Subsequent treatment with
lithium hexamethyldisilazide (
LiHMDS) and
TMSCl gave the TMS-protected
silyl enol ether,
which was immediately...
