-
between aldimines and
ketimines,
derived from
aldehydes and ketones, respectively. In
imines the five core
atoms (C2C=NX,
ketimine; and C(H)C=NX, aldimine;...
- They can be
considered a sub-class of imines,
being either secondary ketimines or
secondary aldimines depending on
their structure. Anil
refers to a...
- to use
alkynyl ketimines as
synthetic equivalents of
dialkyl ketimines, and
dialkyl ketimes are a
typical example of
isomeric ketimine mixtures. The alkynyl...
- Solinas,
Sandro P.; Fontana,
Mario (1991). "Sulfur-containing
cyclic ketimines and
imino acids. A
novel family of
endogenous products in the
search for...
- intermediate. with
Grignard reagents to form
primary ketimines in the Moureau-Mignonac
ketimine synthesis.
While not a
classical Grignard reaction, it...
- intermediate.
Ketimine formation: The qui****id is reprotonated, but now at the
aldehyde carbon, to form the
ketimine intermediate.
Ketimine hydrolysis:...
-
Hydrazone R'R"CN2H2 hydrazino- -hydrazine
Imine Primary ketimine RC(=NH)R' imino- -imine
Secondary ketimine RC ( = NR ″ ) R ′ {\displaystyle {\ce {RC(=NR'')R'}}}...
- (help) Verardo, G.; Giumanini, A. G.; Strazzolini, P.; Poiana, M. (1988). "
Ketimines From
Ketones and Ammonia".
Synthetic Communications. 18 (13): 1501–1511...
-
synthesis of
chiral amines from
ketimines using a
chiral alkoxide. The
addition of a
phosphinoyl group to the
nitrogen of the
ketimine allowed for high enantioselectivity...
-
intermediate accepts a
proton at a
different position to
become a
ketimine. The
resulting ketimine is
hydrolysed so that the
amino group remains on the complex...
