-
outweighed by the fact that
isonitriles can be
detected even in traces, and that most of the
routes leading to the
formation of
isonitriles were
discovered through...
- The
carbylamine reaction (also
known as the
Hoffmann isocyanide synthesis) is the
synthesis of an
isocyanide by the
reaction of a
primary amine, chloroform...
-
Methyl isocyanide or
isocyanomethane is an
organic compound and a
member of the
isocyanide family. This
colorless liquid is
isomeric and isoelectronic...
- amines. Hofmann's
discoveries include formaldehyde, hydrazobenzene, the
isonitriles, and
allyl alcohol. He
prepared three ethylamines and tetraethylammonium...
-
Isocyanide dichlorides are
organic compounds containing the RN=CCl2
functional group.
classically they are
obtained by
chlorination of isocyanides. Phenylcarbylamine...
- fluoropolymers, like PFOA. Trifluoromethylisocyanide, the
simplest perfluorinated isonitrile. Trifluoromethylacetonitrile, the
simplest perfluorinated nitrile. Triflic...
-
reagent in dehydrations. One
example involves conversion of
formamides to
isonitriles (isocyanides);
primary amides to nitriles: RC(O)NH2 + POCl3 → RCN + P(O)OHCl...
-
pnictogen atoms can be
synthesized via the
insertion of
carbon monoxide and
isonitriles into the
corresponding pnictogen-centered cyclobutane-1,3-diyls. In 2015...
-
cyanates (ROCN),
isocyanates (RNCO),
nitrates (RONO2),
nitriles (RCN),
isonitriles (RNC),
nitrites (RONO),
nitro compounds (RNO2),
nitroso compounds (RNO)...
-
coordination compounds containing nitrile ligands,
which are
isomers of
isonitriles Underwood, S. R.; Anagnostopoulos, C.; Cerqueira, M.; Ell, P. J.; Flint...