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Iodosobenzene or
iodosylbenzene is an
organoiodine compound with the
empirical formula C6H5IO. This
colourless solid compound is used as an oxo transfer...
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hypervalent iodine reagents used to
effect these transformations include iodosylbenzene (PhIO), Koser's
reagent (PhI(OTs)OH), and (dichloroiodo)benzene (PhICl2)...
- well as Mn(porphyrin) systems. The
zeolite studies generally emplo****
iodosylbenzene (PhIO),
rather than TPHP as oxidant. The
difference is
likely mechanistically...
- 11-tetramethyl-1,4,8,11-tetraazacyclotetradecane; OTf = CF3SO3, with
iodosylbenzene (PhIO) in CH3CN at -40 ˚C. A
second method for
formation of
cyclam oxoiron(IV)...
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catalyzed by a
synthetic iron(III)
porphyrin complex, Fe(TPP)Cl
using an
iodosylbenzene (PhIO) oxidant. In the reactions,
alkenes and
alkanes were oxidized...
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epoxidation catalyzed by iron-porphine complexes.
Oxygen transfer from
iodosylbenzene". J. Am. Chem. Soc. 101 (4): 1032–1033. doi:10.1021/ja00498a040. Chen...
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ligands in electron-rich
complexes are
susceptible to oxidation, e.g. by
iodosylbenzene.
Nitriles undergo coupling with alkenes, also
involving electron-rich...