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Iminophosphorane (or, more correctly, phosphanimine) is a kind of
organophosphorus compound with the
formula R3PNR'. Like the
corresponding phosphine oxides...
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reaction of an
organic azide with a
phosphine or
phosphite produces an
iminophosphorane. The
reaction was
discovered by and
named after Hermann Staudinger...
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chemical reaction of a
carbonyl group with an aza-ylide, also
known as an
iminophosphorane (R3P=NR'). Aza-Wittig
reactions are most
commonly used to
convert aldehydes...
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iminophosphorane (Figure 2). This reaction,
commonly referred to as the
Staudinger reaction,
typically produces a high
yield of the
iminophosphorane....
- have the
formula R−N=P(−NR2)3.
These phosphazenes are also
known as
iminophosphoranes and
phosphine imides. They are superbases.
Another class of compounds...
- Guanglong; Farley,
Alistair J. M.; Dixon,
Darren J. (2020). "Bifunctional
Iminophosphorane Superbase Catalysis:
Applications in
Organic Synthesis".
Accounts of...
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organic azide is not
available to
generate the
iminophosphorane. Thus, it is used to make
iminophosphoranes from
alkyl amines. Eguchi, Shoji; Matsu****a...
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carbenoids (produced from
diazocarbonyl compounds). The
reaction of
iminophosphoranes and
organic azides in an Aza-Wittig-reaction.
Condensation of carbon...
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which transforms the
yellow λ3σ3 1H-2-iminophosphete into a λ5σ4
iminophosphorane product.
Streubel et al. (1999)
explored the
reaction of phosphirene-metal...
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Probably the most
famous is the
reaction with phosphines,
which leads to
iminophosphoranes 22;
these can be
hydrolysed into
primary amines 23 (the Staudinger...
