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Zeolitic imidazolate frameworks (ZIFs) are a
class of metal-organic
frameworks (MOFs) that are
topologically isomorphic with zeolites. ZIFs are composed...
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Imidazolate (C3H3N− 2) is the
conjugate base of imidazole. It is a
nucleophile and a
strong base. The free
anion has C2v symmetry.
Imidazole has a pKa...
- Zero
Intermediate Frequency, a
radio demodulation technique Zeolitic imidazolate frameworks, a
class of metal-organic
frameworks Zif, Hebron, a Palestinian...
-
coordination of
histidine to heme complexes. It can be
deprotonated to make
imidazolate-based
coordination polymers. 2-Methylimidazole is a
precursor to the...
- (to give
imidazolate) is 14, thus it is easy to deprotonate? high pKa - low Ka - hard deprotonation. Many
metal complexes feature imidazolate as a bridging...
- Vereecken, P; Ameloot, R (2015). "Chemical
vapour deposition of
zeolitic imidazolate framework thin films".
Nature Materials. 15 (3): 304–10. Bibcode:2016NatMa...
- relationships. Main MOF
systems that have been
explored are
zeolitic imidazolate frameworks (ZIFs),
Carboxylate MOFs, Zirconium-based MOFs,
among others...
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anion are also well known;
these salts are
known as
imidazolates (for example,
sodium imidazolate, NaC3H3N2). Benzimidazole, an
analog with a
fused benzene...
- (triphenylimidazole). When in
basic solution, this
compound converts to the
imidazolate,
which reacts with
oxygen to
eventually give a dioxetane. Fragmentation...
- to
speed up
similar reactions involving alkali carbonates.
Zeolitic imidazolate frameworks (ZIFs) are metal–organic
frameworks similar to zeolites. Because...