- phosphorus-centered
hypervalent molecules. The
theoretical basis for
hypervalency was not
delineated until J.I. Musher's work in 1969. In 1990, Magnusson...
- A
covalent bond is a
chemical bond that
involves the
sharing of
electrons to form
electron pairs between atoms.
These electron pairs are
known as shared...
- in the 2s and 2p s****,
resulting in very high electronegativities.
Hypervalency is
almost unknown in the 2p
elements for the same reason,
because the...
-
radial nodes in the 3p
orbitals of
silicon suggests the
possibility of
hypervalence, as seen in five and six-coordinate
derivatives of
silicon such as SiX−...
-
Schleyer Pv,
Robinson GH (2010). "Carbene
Stabilization of Di****nic: From
Hypervalency to Allotropy". Chemistry: A
European Journal. 16 (2): 432–5. doi:10.1002/chem...
- amine-oxide
compounds Durrant,
Marcus C. (2015). "A
quantitative definition of
hypervalency".
Chemical Science. 6 (11): 6614–6623. doi:10.1039/C5SC02076J. PMC 6054109...
-
singular due to its
small size, low polarisability, and
inability to show
hypervalence. As
another difference,
chlorine has a
significant chemistry in positive...
- Robinson,
Gregory H. (2010). "Carbene
Stabilization of Di****nic: From
Hypervalency to Allotropy". Chemistry: A
European Journal. 16 (2): 432–5. doi:10.1002/chem...
- rule in its
first row, but
elements in
subsequent rows
often display hypervalence. The p-block
elements show
variable oxidation states usually differing...
- doi:10.1063/1.469263. Woon,
David E.; Dunning, Thom H. (2009). "Theory of
Hypervalency:
Recoupled Pair
Bonding in SFn (n = 1−6)". The
Journal of
Physical Chemistry...
