- In
organic chemistry,
hyperconjugation (σ-conjugation or no-bond resonance)
refers to the
delocalization of
electrons with the parti****tion of
bonds of...
- In
organic chemistry,
negative hyperconjugation is the
donation of
electron density from a
filled π- or p-orbital to a
neighboring σ*-orbital. This phenomenon...
-
substituted the carbocation, the more
stable it is, due to
induction and
hyperconjugation. The
major product of the
addition reaction will be the one formed...
-
interactions of the
substituents as well as
orbital interactions such as
hyperconjugation are
responsible for the
relative stability of
conformers and their...
-
widely accepted explanation is that
there is a
stabilizing interaction (
hyperconjugation)
between the
unshared electron pair on the
endocyclic heteroatom (within...
-
Negative hyperconjugation is a
theorized phenomenon in
organosilicon compounds, in
which hyperconjugation stabilizes or
destabilizes certain ac****ulations...
- is
perhaps the
strongest candidate, with the
stabilizing effect of
hyperconjugation on the
staggered conformation contributing to the phenomenon. Theoretical...
- are two main
explanations for the
gauche effect:
hyperconjugation and bent bonds. In the
hyperconjugation model, the
donation of
electron density from the...
- are two main
explanations for the
gauche effect:
hyperconjugation and bent bonds. In the
hyperconjugation model, the
donation of
electron density from the...
- misunderstanding. Due to
early experimentation,
before an
understanding of
hyperconjugation,
results such as the more
rapid nitration of
toluene compared to benzene...
