- In
organic chemistry, a
hydroxy ketone (often
referred to
simply as a ketol) is a
functional group consisting of a
ketone (>C=O)
flanked by a hydroxyl...
-
discovered that IBX is a
valuable reagent for the
transformation of β-
hydroxyketones to β-****tones. IBX
provides yields superior to both the
Swern and Dess–Martin...
-
Buisson (24
February 2015).
Aromatic Hydroxyketones:
Preparation &
Physical Properties:
Aromatic Hydroxyketones from
Butanone (C4) to Dotriacontanone...
-
dithioacetals can
yield ketones, β-
hydroxyketones, α-
hydroxyketones, 1,2-****tones and α-aminoketones. Notably, α-
hydroxyketones and 1,2-****tones can not be...
- to
alkenes in
ester pyrolysis.
Pairs of
esters are
coupled to give α-
hydroxyketones in the
acyloin condensation As a class,
esters serve as
protecting groups...
- Me(Et)C=NNH2 + H2O α-
Hydroxyketones, or acyloins, are an
important synthetic motifs present in many
natural products. α-
Hydroxyketones have been synthesized...
-
notably 2,3-epoxy-alcohols and type 4
concerns the
reactions of
alpha hydroxyketones and
alpha hydroxy imines.
Reactions of type 4 are also
called acyloin...
-
reduction for the
stereoselective generation of syn-1,3-diols from β-
hydroxyketones.
Triethylborane is
strongly pyrophoric, with an
autoignition temperature...
- alkylhydroxylamines, dithionates,
reducing saccharides (e.g. glucose), α-
hydroxyketones (e.g., hydroxyacetone),
substituted boron hydrides and
silicon hydrides...
-
Sulfene can
undergo cycloadditions to form
various heterocycles. α-
Hydroxyketones react with
sulfene to form five-membered sultones.
Forming acyliminium...
