-
substitution on
phenols in a Friedel–Crafts
hydroxyalkylation.
Enantioselective ortho-
hydroxyalkylation mediated by
chiral alkoxyaluminum chlorides Franca...
- The Friedel–Crafts
reactions are a set of
reactions developed by
Charles Friedel and
James Crafts in 1877 to
attach substituents to an
aromatic ring. Friedel–Crafts...
-
sulfite esters,
which can be
powerful methylation,
alkylation and
hydroxyalkylation reagents. SOCl2 + 2 R−OH → (R−O)2SO + 2 HCl For example, the addition...
-
component is
broad diverse. The key
attribute is
susceptibility toward hydroxyalkylation. The
related resorcinarenes and
pyrogallolarenes are
produced from...
- 2011.01.017. ISSN 2210-271X. Zarzyka-Niemiec,
Iwona (2008-10-05). "
Hydroxyalkylation of
oxamic acid with
propylene carbonate: Synthesis, composition, and...
- diols, such as sugars.
Sulfite esters can be
powerful alkylation and
hydroxyalkylation reagents. Mono-esters, with the
general structure (RO)(HO)S=O are...
- "α-C–H
Functionalization of π-Bonds
Using Iron Complexes:
Catalytic Hydroxyalkylation of
Alkynes and Alkenes".
Journal of the
American Chemical Society...
- "α-C–H
Functionalization of π-Bonds
Using Iron Complexes:
Catalytic Hydroxyalkylation of
Alkynes and Alkenes".
Journal of the
American Chemical Society...
-
Calixarenes are the
general category of
macrocycle oligomers formed by
hydroxyalkylation of a
phenol and an aldehyde;
Resorcinarenes are one example. Calixarenes...
- deprotonation,
forming a selenium-substituted enolate,
allows alkylation or
hydroxyalkylation of
these substrates. (7) Base-sensitive
substrates may be selanylated...