-
Hydrosilylation, also
called catalytic hydrosilation,
describes the
addition of Si-H
bonds across unsaturated bonds.
Ordinarily the
reaction is conducted...
-
alkenylboranes and
phosphines are
beneficial for
asymmetric Piers-type
hydrosilylations of 1,2-dicarbonyl
compounds and alpha-keto esters,
giving high yield...
- such as
esterifications with anhydrides, the Baylis-Hillman reaction,
hydrosilylations, tritylation, the
Steglich rearrangement,
Staudinger synthesis of β-lactams...
- chlorosilanes.
Another major method for the
formation of Si-C
bonds is
hydrosilylation (also
called hydrosilation). In this process,
compounds with Si-H bonds...
-
complexes with
silanes produces metal nanoparticle that
catalyze the
hydrosilylation reaction. BINAP-functionalized
palladium nanoparticles and gold nanoparticles...
-
chemical vapor deposition process called the
Siemens process. Via
hydrosilylation,
trichlorosilane is a
precursor to
other useful organosilicon compounds:...
- divinyl-containing disiloxane. This
coordination complex is
widely used in
hydrosilylation catalysis. It is a
colorless solid that is
generally ****umed to be...
-
involving hydrogen gas and hydrosilanes.
These include hydrogenations and
hydrosilylations of alkenes.
Rhodium metal, but not
rhodium complexes,
catalyzes the...
- ferrocene.
Cobalt carbonyl (Co2(CO)8) is a
catalyst in
carbonylation and
hydrosilylation reactions.
Vitamin B12 (see below) is an
organometallic compound found...
- in
homogeneous catalysis, e.g., hydrogenations, hydroformylations,
hydrosilylations, etc. Cross-coupling
reactions like the
Suzuki coupling,
Negishi coupling...
