-
hydrogenolysis is
conducted catalytically using hydrogen gas. The term "
hydrogenolysis" was
coined by
Carleton Ellis in
reference to
hydrogenolysis of...
- net
result of a
hydrogenolysis reaction is the
formation of C-H and H-X
chemical bonds. Thus,
hydrodesulfurization is a
hydrogenolysis reaction. Using...
-
preferred over
palladium catalysts to
minimize hydrogenolysis. The
catalyst is also used for the
hydrogenolysis of
phenyl phosphate esters, a
reaction that...
-
common catalyst for
hydrogenolysis. Such
reactions are
helpful in
deprotection strategies.
Particularly common substrates for
hydrogenolysis are
benzyl ethers:...
- by
hydrogenolysis p-Methoxybenzyl (PMB) –
Removed by
hydrogenolysis, more
labile than
benzyl 3,4-Dimethoxybenzyl (DMPM) –
Removed by
hydrogenolysis, more...
- the
reaction of
methylamine and
diethylene glycol as well as by the
hydrogenolysis of N-formylmorpholine. It is the
precursor to N-methylmorpholine N-oxide...
-
formula (CH3)2CHC6H10CH3. It is the
product of the
hydrogenation or
hydrogenolysis of
various terpenoids,
including p-cymene, terpinolenes, p****andrene...
- terephthalate. It is
generated both by the
oxidation of p-xylene as well as the
hydrogenolysis of 4-carboxybenzaldehyde. In
related processes it is
converted to methyl...
- ammonia,
since after N-alkylation, the
benzyl group can be
removed by
hydrogenolysis: C6H5CH2NH2 + 2 RBr → C6H5CH2NR2 + 2 HBr C6H5CH2NR2 + H2 → C6H5CH3 +...
- an
isocyanate with
benzyl alcohol (as in the
Curtius rearrangement).
Hydrogenolysis in the
presence of a
variety of palladium-based
catalysts is the usual...
