-
widely used in a catalyst-free
hydroborations.
Carboboration metal-catalysed
hydroboration Brown, H.C. (1961). "
Hydroboration-A
Powerful Synthetic Tool"....
-
Hydroboration–oxidation
reaction is a two-step
hydration reaction that
converts an
alkene into an alcohol. The
process results in the syn
addition of...
-
experimental ease of its use, BMS has
become common in
hydroboration reactions. In
hydroborations with BMS, the
dimethylsulfide dissociates in situ, liberating...
- with Wilkinson's Catalyst:Implications for
Transition Metal-Catalyzed
Hydroborations of Alkenes".
Journal of the
American Chemical Society. 114 (24): 9350–9359...
- for the
conversion of
terminal olefins into
alkylmercuric salts via
hydroboration-mercuration".
Journal of the
American Chemical Society. 92 (8): 2467–2471...
- Brown, H. C. (1983). "The
Dimesitylboron Group in
Organic Chemistry. 6
Hydroborations with dimesitylborane".
Tetrahedron Letters. 24 (13): 1433. doi:10...
-
hydrofunctionalization reactions including hydroacylation,
hydroboration, and
hydrosilylation of alkenes.
Hydroborations have been
studied with
catecholborane and pinacolborane...
-
substitution with
acids is not possible. In this case, one has to use the
hydroboration–oxidation reaction,
wherein the
first step, the
boron atom acts as electrophile...
-
ammonia borane as byproduct. The
ratio depends on the conditions. In the
hydroboration reaction,
diborane also
reacts readily with
alkenes to form trialkylboranes...
-
known and many are
useful in
organic synthesis. Many are
produced from
hydroboration,
which employs diborane, B2H6, a
simple borane chemical, or carboboration...
