- choice, it can
react with carbon-carbon
multiple bonds (i.e.,
through hydroalumination).
Given its density, and with
hydrogen content on the
order of 10%...
-
group attached to
aluminium to an
electrophilic atom.
Stereospecific hydroalumination, carboalumination, and
terminal alkyne metalation are
useful methods...
-
Organoaluminium chemistry is the
study of
compounds containing bonds between carbon and aluminium. It is one of the
major themes within organometallic...
- they
observed reverse selectivity for β with Ni(PPh3)2Cl2 in
their hydroalumination reactions under same
conditions with
little or no byproducts. The advantage...
-
synthetic advances include the
dehydrobromination of
phosphaalkenes the
hydroalumination of alkynylphosphines. The Phospha-Wittig-Horner reaction,
first reported...
-
alkylaluminium reagents results in
lowered yield, due to the
formation of the
hydroalumination product (via β-hydrogen
elimination of the
alkylzirconium intermediate)...
- Dzhemilev, U. M. (2011). "DFT and Ab
Initio Study on
Mechanism of
Olefin Hydroalumination by XAlBui2 in the
Presence of Cp2ZrCl2 Catalyst. II.(1)
Olefin Interaction...
-
reaction product is a vinylorganometallic.
Examples are hydroboration,
hydroalumination,
hydrosilylation and hydrozirconation. Elschenbroich, C. ”Organometallics”...
-
addition yielded the
unsaturated alcohol product.
Alkenes undergo hydroalumination in the
presence of some
alkoxyaluminium hydrides. In a
related application...
- Soc.: 229–232. doi:10.1039/JR9630000229. Uhl, W.; Matar, M. (2004). "
Hydroalumination of
nitriles and isonitriles" (PDF). Z. Naturforsch. B. 59 (11–12):...
