-
homogeneous solution. Instead, many
compounds have
hydrogen centres with
hydridic character.
Aside from electride, the
hydride ion is the
simplest possible...
-
Primordially Hydridic Earth concept[dubious – discuss] that
described deep-seated
natural hydrogen prominence and
migration paths.
Larin V.N. 1975
Hydridic Earth:...
- It is a
brick red, air-sensitive solid. Stryker's
reagent is a
mildly hydridic reagent, used in
homogeneous catalysis of
conjugate reduction reactions...
- loosely: some of them are
acidic (e.g., H2Fe(CO)4),
whereas some
others are
hydridic,
having H−-like
character (e.g., ZnH2). Many
transition metals form compounds...
-
highly polar nature of
ammonia borane. The H
atoms attached to
boron are
hydridic (negatively charged) and
those attached to
nitrogen are
acidic (positively...
- is polymeric. In
lithium aluminium hydride, the [AlH4]−
anion carries hydridic centers firmly attached to the Al(III).
Although hydrides can be formed...
- hydrides. It is
converted to the
bromide B3H7Br−
using HBr (illustrating its
hydridic character): B3H8− + HBr → B3H7Br− + H2
Pyrolysis of this
bromide gives...
- is polymeric. In
lithium aluminium hydride, the [AlH4]−
anion carries hydridic centers firmly attached to the Al(III).
Although hydrides can be formed...
- in
common organic solvent and water.
Because of the
uniqueness of its
hydridic B-H
vertices and
charge delocalization, the [CoD]−
anion exhibits surface...
- Hδ−. In
other words, the
amine is a
protic acid and the
borane end is
hydridic. The
resulting B−H...H−N
attractions stabilize the
molecule as a solid...
