- In chemistry,
homolysis (from Gr**** ὅμοιος (homoios) 'equal' and λύσις (lusis) 'loosening') or
homolytic fission is the
dissociation of a
molecular bond...
- on the
stability of a
given compound, and some weak
bonds are able to
homolyze at
relatively lower temperatures. Some
homolysis reactions are particularly...
- side reaction. The
process is
typically initiated with persulfate,
which homolyzes to
generate sulfate radicals: [O3SO−OSO3]2− ⇌ 2 SO•− 4 The
resulting polymer...
- of polyethylene. A key step is homolysis: ROOR ⇌ 2 RO. The
tendency to
homolyze is also
exploited to
modify polymers by
grafting or visbreaking, or cross-link...
- polymethylhydrosiloxane. The
thiobenzoyl radical intermediates formed when the
ester homolyzes fragment into
carbonyl sulfide and
phenyl radicals before forming tributyltin...
-
chlorination of
methane as an example:
Initiation Ultraviolet radiation splits (
homolyzes) a
chlorine molecule to two
chlorine atom radicals.
Chain propagation...
- component. The
process is
typically initiated with peroxydisulfate,
which homolyzes to
generate sulfate radicals.
Because FEP is
poorly soluble in almost...
- (ONOOCO− 2) is by far the
predominant pathway for ONOO−. ONOOCO− 2
homolyzes to form
carbonate radical and
nitrogen dioxide,
again as a pair of caged...
- N-chloroamine, which, in the
presence of heat, light, or
other initiators,
homolyzes to
ammonium and
chloride free radicals. The
ammonium radical intramolecularly...
- and
carbonates were
found to
mediate mechano/sono-ATRP.
Mechochemically homolyzed water molecules undergoes radical addition to monomers,
which in turn...
