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Homoaromaticity, in
organic chemistry,
refers to a
special case of
aromaticity in
which conjugation is
interrupted by a
single sp3
hybridized carbon atom...
- boron) for "normal"
aromatic stabilization to be available; otherwise,
homoaromaticity may be possible.
Borazocine is an eight-membered ring with four nitrogen...
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compounds called cyclophanes. A
special case of
aromaticity is
found in
homoaromaticity where conjugation is
interrupted by a
single sp³
hybridized carbon...
- 1964 in the
group of R. B.
Woodward in
connection with its
suspected homoaromatic properties—though it was
found to have no such properties—and also as...
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alphabet (α-γ) and the
substitution pattern nomenclature common for
homoaromatic systems (ortho, meta, para) are used sometimes. Here α (ortho), β (meta)...
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Homonaphthalene has been used in the
production of
conductive polymers.
Homoaromaticity Cyclodecapentaene 1,5-Methano[10]annulene Vogel, Emanuel; Klug, W.;...
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stability due to the
phenomenon called "three-dimensional aromaticity" or
homoaromaticity. This four-center two-electron bond
involves one pair of electrons...
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derived from
delocalization of
positive charge (see the
article on
homoaromaticity for details.).
Neutral systems generally require constrained geometries...
- 2004 Brookhart, Maurice; Ogliaruso,
Michael A.; Winstein, Saul. The
homoaromatic 1-hydroxyhomotropylium cation.
Journal of the
American Chemical Society...
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Tetrahedral Topology.
Experimental Realization of Three-Dimensional
Homoaromaticity in the 1,3-Dehydro-5,7-adamantanediyl Dication".
Angewandte Chemie...
