- In
organic chemistry,
neighbouring group parti****tion (NGP, also
known as
anchimeric ****istance) has been
defined by the
International Union of Pure and...
- an
allyl sulfide reacts with
trimethylsilyldiazomethane to form the
homoallyl sulfide compound. The
reaction was
first reported by
Wolfgang Kirmse [de]...
-
iodine and the
organic residue R′ is alkenyl, aryl, allyl, alkyl, benzyl,
homoallyl, and homopropargyl. The
metal M in the
catalyst is
nickel or palladium...
-
allyl halides by
means of
chromous salt. A
chemospecific synthesis of
homoallyl alcohols Yo****aka Okude,
Shigeo Hirano,
Tamejiro Hiyama,
Hitoshi Nozaki...
- Doyle–Kirmse reaction,
certain diazo compounds react with
allyl sulfides to the
homoallyl sulfide.
Intramolecular reactions of
diazocarbonyl compounds provide access...
- (C1),
methyl iodide (C1), 2,3-dibromopropene (C3),
acetic acid (C2) and
homoallyl bromide (C4). The
lower rim of the
cyclooctane B ring
containing the first...
- −61 °C.
Three other possible structures, two
classical structures (the
homoallyl cation and
cyclobutyl cation) and a more
highly delocalized non-classical...
-
bicyclic structure.
Solvolyses of cyclopropylcarbinyl, cyclobutyl, and
homoallyl esters are also
characterized by very
large rates, and have been shown...
- "Diastereoselective
synthesis of trans-1,2-disubstituted
cyclopropanols from
homoallyl or bis-
homoallyl esters via
tandem intramolecular nucleophilic acyl substitution...
-
September 1976). "Allylsilanes as
synthetic intermediates. ii.
syntheses of
homoallyl ethers from
allylsilanes and
acetals promoted by
titanium tetrachloride"...
