Definition of Hemilabile. Meaning of Hemilabile. Synonyms of Hemilabile

- dictate the turn-over rate of the catalyst and hence its effectiveness. Hemilabile ligands reduce the activation energy of these changes by readily undergoing...
- Mirkin Group at Northwestern University. This method takes advantage of hemilabile ligands -ligands that contain both strong and weak binding moieties- that...
- are used in homogeneous catalysis, such as asymmetric hydrogenation. Hemilabile ligands contain at least two electronically different coordinating groups...
- organometallic chemistry and homogeneous catalysis. It is the prototypical hemilabile ligand. This compound is prepared from 2-bromoanisole. Tris(4-methoxyphenyl)phosphine...
- Lin, Zhi-Wei; Wang, Quan-Ming (2012). "Au20 Nanocluster Protected by Hemilabile Phosphines". Journal of the American Chemical Society. 134 (36): 14750–14752...
- PHOX ligands are distinctive. Some evidence exists that PHOX ligands are hemilabile. The synthesis of phosphinooxazolines is modular. Methods exist for installing...
- complex itself helps enforce the final geometry. In the weak link method, a hemilabile ligand is used: a weak metal-heteroatom bond is the 'weak link.' The formation...
- Bühl, Michael (2019). "Design of a Highly Active Pd Catalyst with P,N Hemilabile Ligands for Alkoxycarbonylation of Alkynes and Allenes: A Density Functional...
- Numerous crystallographic studies have indicated that it behaves as a hemilabile ligand and is believed to play a role in stabilizing the highly reactive...
- asymmetric examples through the usage of chiral phosphine ligand with a hemilabile coordinating group. This method was applicable using vinylarenes, 1,3-dienes...