-
dictate the turn-over rate of the
catalyst and
hence its effectiveness.
Hemilabile ligands reduce the
activation energy of
these changes by
readily undergoing...
- are used in
homogeneous catalysis, such as
asymmetric hydrogenation.
Hemilabile ligands contain at
least two
electronically different coordinating groups...
-
Mirkin Group at
Northwestern University. This
method takes advantage of
hemilabile ligands -ligands that
contain both
strong and weak
binding moieties- that...
-
organometallic chemistry and
homogeneous catalysis. It is the
prototypical hemilabile ligand. This
compound is
prepared from 2-bromoanisole. Tris(4-methoxyphenyl)phosphine...
- Lin, Zhi-Wei; Wang, Quan-Ming (2012). "Au20
Nanocluster Protected by
Hemilabile Phosphines".
Journal of the
American Chemical Society. 134 (36): 14750–14752...
- PHOX
ligands are distinctive. Some
evidence exists that PHOX
ligands are
hemilabile. The
synthesis of
phosphinooxazolines is modular.
Methods exist for installing...
- Rodolphe; Melaimi, Mohand; Bertrand, Guy (2016-06-29). "Synthesis of
Hemilabile Cyclic (Alkyl)(amino)carbenes (CAACs) and
Applications in Organometallic...
-
complex itself helps enforce the
final geometry. In the weak link method, a
hemilabile ligand is used: a weak metal-heteroatom bond is the 'weak link.' The formation...
-
asymmetric examples through the
usage of
chiral phosphine ligand with a
hemilabile coordinating group. This
method was
applicable using vinylarenes, 1,3-dienes...
- Bühl,
Michael (2019). "Design of a
Highly Active Pd
Catalyst with P,N
Hemilabile Ligands for
Alkoxycarbonylation of
Alkynes and Allenes: A
Density Functional...
