- of some
readily isolable hemiacetals and hemiketals.
Chloral and
ethyl glyoxalate illustrate the
stabilizing influence of electron-withdrawing groups. The...
- 2-phosphoglycolate, a 2-carbon
molecule that can be
converted via
glycolate and
glyoxalate to glycine. Via the
glycine cleavage system and tetrahydrofolate, two...
- from the
coupling reaction with a
vinyl Grignard reagent and a
silyl glyoxalate to form a nitrocylopentanol. This
process via a
Henry reaction and is...
- It is
produced biologically by the
condensation of two
equivalents of
glyoxalate: 2 OC(H)CO2H → OC(H)CH(OH)CO2H + CO2 This
condensation is
catalyzed by...
- N-alkylglycine + H2O + O2 ⇌ {\displaystyle \rightleftharpoons }
alkylamine +
glyoxalate + H2O2
Isolated from the mold
Cladosporium sp. G-10. Gomi K, Horiuchi...
-
Baizer (1983), "Electrogenerated
bases VII.
Novel syntheses of
ethyl glyoxalate and
diethyl ketomalonate via
electrogenerated superoxide", Tetrahedron...
-
hydroxymalonic semialdehyde carboxylase,
tartronic semialdehyde carboxylase,
glyoxalate carboligase, and
glyoxylate carboxy-lyase (dimerizing). This
enzyme parti****tes...
-
manufactures synthetic dry
strength resins which are
acrylamide based,
glyoxalated (FLOSTRENGTH) or
issued from
Hofmann rearrangement.
These resins, applied...
- PMID 4320439.
Stewart PR,
Quayle JR (1967). "The
synergistic decarboxylation of
glyoxalate and 2-oxoglutarate by an
enzyme system from pig-liver mitochondria". Biochem...