-
material to
synthesize the
glycal.
Glycals can also be
classified as endo-
glycals or exo-
glycals. A
glycal is an endo-
glycal when the
double bond is within...
-
nucleophilic substitution reaction combined with an
allylic shift in a
glycal (a 2,3-unsaturated glycoside). It was
discovered by the
carbohydrate chemist...
- synthesis.
These compounds are
conjugates of
amino sugars and aminocy****ols.
Glycals are
cyclic enol
ether derivatives of monosaccharides,
having a
double bond...
-
Glucal is the
glycal formed from glucose. It is a
chemical intermediate in the
synthesis of a
variety of oligosaccharides.
Glucal and its
derivatives can...
- 2012). "Biosynthesis of the
tunicamycin antibiotics proceeds via
unique exo-
glycal intermediates".
Nature Chemistry. 4 (7): 539–546. Bibcode:2012NatCh...4...
- acetates, thioglycosides, trichloroacetimidates,
pentenyl glycosides, and
glycals. Of all
these donors,
glycosyl halides are
classic donors,
which pla****...
- "Alternative
Syntheses of L-(-)-Oleandrose from L-Rhamnose1Preparation of
Glycals".
Synthetic Communications. 22 (17): 2459–2477. doi:10.1080/00397919208021642...
-
latter is a
particularly significant problem for phenols). Enol
ethers and
glycals are
nucleophilic enough to be
fluorinated by Selectfluor.
Similar to other...
- Taylor, R. J. K. (August 2002). "ChemInform Abstract: A New
Route to exo-
Glycals Using the Ramberg–Baecklund Rearrangement". ChemInform. 33 (33): 1305....
- P. Sinaÿ, « Organoselenium chemistry :
stereoselective conversion of
glycals into
anomeric spiroorthoesters using a glycosyloxyselenation- oxidation...
