-
germylenes have
exclusively a
singlet ground state.
Unprotected carbene analogs,
including germylenes, has a
dimerization nature. Free
germylenes can...
-
derivatives of
germabenzene and 1,2-digermabenzene,
analogues of benzene.
Germylenes (carbene analogues) and
germyl free
radicals have been investigated. Reaction...
- Germanium(II) hydrides, also
called germylene hydrides, are a
class of
Group 14
compounds consisting of low-valent
germanium and a
terminal hydride. They...
- Many
germanium reactive intermediates are known:
germyl free radicals,
germylenes (similar to carbenes), and
germynes (similar to carbynes). The organogermanium...
- Many
germanium reactive intermediates are known:
germyl free radicals,
germylenes (similar to carbenes), and
germynes (similar to carbynes). The organogermanium...
-
dimerize via the halogen-bridging mode,
monohalogenated silylenes and
germylenes tend to
dimerize via the
abovementioned multiply-bonded mode instead....
-
entirely due to π interactions. For comparison, in an
analogous way,
germylenes have a
charge near +1 at the
germanium while cabenes have
close to no...
- or boranylidene. The
heavier group 14
carbenes are silylenes, R2Si:,
germylenes R2Ge: (example diphosphagermylene),
stannylenes R2Sn: and plumbylenes...
- 1016/S0040-4039(00)99955-6. Wang, Yong; Ma, Jing (2009). "Silylenes and
germylenes: The
activation of H–H bond in
hydrogen molecule".
Journal of Organometallic...
-
diphosphagermylene could not be investigated. The
sterically en****bered
germylene ligand (Dipp)2PH,
where Dipp=2,6-iPr2C6H3, was
synthesized by the addition...
