-
germylenes have
exclusively a
singlet ground state.
Unprotected carbene analogs,
including germylenes, has a
dimerization nature. Free
germylenes can...
- Germanium(II) hydrides, also
called germylene hydrides, are a
class of
Group 14
compounds consisting of low-valent
germanium and a
terminal hydride. They...
-
derivatives of
germabenzene and 1,2-digermabenzene,
analogues of benzene.
Germylenes (carbene analogues) and
germyl free
radicals have been investigated. Reaction...
- Many
germanium reactive intermediates are known:
germyl free radicals,
germylenes (similar to carbenes), and
germynes (similar to carbynes). The organogermanium...
-
diphosphagermylene could not be investigated. The
sterically en****bered
germylene ligand (Dipp)2PH,
where Dipp=2,6-iPr2C6H3, was
synthesized by the addition...
- Many
germanium reactive intermediates are known:
germyl free radicals,
germylenes (similar to carbenes), and
germynes (similar to carbynes). The organogermanium...
- MICl(imidazol-2-ylidene) complexes, as well as with the
corresponding silylene and
germylene NHC-type ligands. High metal-ligand bond
dissociation energies of 67.4...
-
entirely due to π interactions. For comparison, in an
analogous way,
germylenes have a
charge near +1 at the
germanium while cabenes have
close to no...
- germirane-substituted
germylene intermediate. Ge atom of the
germirane substituent then
easily inserts into one of the Ge-C
bonds of
germylene to
generate 1...
-
dimerize via the halogen-bridging mode,
monohalogenated silylenes and
germylenes tend to
dimerize via the
abovementioned multiply-bonded mode instead....
