- are
weakly acidic (pKa = 22.6 in DMSO.)
Deprotonation gives the
stable fluorenyl anion,
nominally C13H9−,
which is
aromatic and has an
intense orange colour...
- risk of
aggregation with Fmoc/tBu SPPS however.
Because the
liberated fluorenyl group is a chromop****, Fmoc
deprotection can be
monitored by UV absorbance...
- Cp
ligand is the
cyclopentadienyl group, the
second Cp
ligand is the
fluorenyl group, and the
bridge between the two Cp
ligands is -CH2-CH2-, >SiMe2...
- ISBN 978-3527306732. S. Neander; J. Kornich; F.
Olbrich (2002). "Novel
Fluorenyl Alkali Metal DIGLYME Complexes:
Synthesis and
Solid State Structures"...
- and
aqueous dioxane is also a
method to
install Fmoc group.
Because the
fluorenyl group is
highly fluorescent,
certain UV-inactive
compounds may be reacted...
-
Dennis A.; Maichle-Mössmer, Cäcilia; Anwander,
Reiner (2022). "Cerium
Fluorenyl Complexes Including CC
Coupling Reactions". Organometallics. 41 (8): 962–976...
- Gruppe.
Synthese und
Kristallstruktur von [GaFl3(THF)] ·
Toluol (Fl =
Fluorenyl)".
Zeitschrift für
Anorganische und
Allgemeine Chemie. 623 (1–6): 394–402...
-
direct methanol fuel cell (DMFC) or direct-ethanol fuel cell (DEFC). Poly(
fluorenyl-co-aryl piperidinium) (PFAP)-based
anion exchange materials (electrolyte...
-
presence of a
reducing agent, loss of N2
occurs to
generate a DNA-cleaving
fluorenyl radical. One
biochemical process for
diazo formation is the L-aspartate-nitro-succinate...
- also
observed in a
number of non
indenyl substituted metal complexes. In
fluorenyl complexes, ****ociative
substitution is
enhanced even
further than indenyl...
