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Boron trifluoride etherate,
strictly boron trifluoride diethyl etherate, or
boron trifluoride–ether complex, is the
chemical compound with the formula...
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adduct with
diethyl ether,
boron trifluoride diethyl etherate, or just
boron trifluoride etherate, (BF3·O(CH2CH3)2) is a
conveniently handled liquid and...
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diethyl ether forms a
complex with
boron trifluoride, i.e.
borane diethyl etherate (BF3·O(CH2CH3)2).
Ethers also
coordinate to the Mg
center in
Grignard reagents...
- (Li+[Cu(CH3)2]−)2. Similarly,
lithium diphenylcuprate(I)
forms a
dimeric etherate, ([Li(O(CH2CH3)2)]+[CuPh2]−)2, in the
solid state. The
involvement of the...
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center does not need to be a metal, as
exemplified by
boron trifluoride etherate BF3OEt2,
where the
highly Lewis acidic, but non-metallic
boron center takes...
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creating the bond. For example, F3B ← O(C2H5)2 ("boron
trifluoride (diethyl)
etherate") is
prepared from BF3 and :O(C2H5)2, as
opposed to the
radical species...
- 19670500235. PMID 5587099.
Gaoni Y,
Mechoulam R (1985). "Boron
trifluoride etherate on alumuna – a
modified Lewis acid reagent. An
improved synthesis of cannabidiol"...
- In
conjunction with
Lewis acidic additives such as
boron trifluoride etherate,
these reagents are used for
conjugate addition reactions. Lower-order...
- as
magnesium bromide,
lithium tetrafluoroborate and
boron trifluoride etherate were also
developed to
deprotect SEM group. Lipshutz,
Bruce H.; Pegram...
-
removed by
reaction with
triethylsilane in the
presence of
boron trifluoride etherate. This route, as well as
others developed for the
manufacture of the drug...
