-
lithium diisopropylamide (LDA, pKa of
conjugate acid ~36)
under non-
equilibrating conditions (–78 °C, 1.1
equiv LDA in THF,
ketone added to base), the...
- _{k=1}^{M}e^{-E_{k}/RT}}}.} The left hand side is the
proportion of
conformer i in an
equilibrating mixture of M
conformers in
thermodynamic equilibrium. On the
right side...
-
prepared by
sulfonation of
naphthalene with
sulfuric acid,
however under equilibrating conditions that
allow the 1-sulfonic acid
isomer to
convert to the more...
-
water drainage flows into
permanent and
seasonal lakes and
swamps that
equilibrate through evaporation.
Endorheic basins are also
called closed basins,...
- the
Great Depression, most
economists believed in Say's law and the
equilibrating powers of the market, and
failed to
understand the
severity of the Depression...
- pre-existing schemas.
Through these two processes,
young children learn by
equilibrating their mental representations with reality. They also
learn from mistakes...
- example, beta-scission of a weak C-S bond was used to
favor one of two
equilibrating radicals in
metal free
conversion of
phenols to
aromatic esters and...
-
names to "the
strong and
impetuous type, the
strong equilibrated and
quiet type, the
strong equilibrated and
lively type, and the weak type", respectively...
-
compound allylpot****ium (KCH2CHCH2). cis-2-Butene and trans-2-butene
equilibrate when in
contact with
alkali metals.
Whereas isomerisation is fast with...
- the
continental slope,
losing salinity,
until they
begin to mix and
equilibrate more rapidly, much ****her out at a
depth of
about 1,000 m (3,300 ft;...
