Definition of Epoxidations. Meaning of Epoxidations. Synonyms of Epoxidations

- complexes are useful catalysts for epoxidations involving hydrogen peroxide and alkyl hydroperoxides. Metal-catalyzed epoxidations were first explored using tert-butyl...
- The Sharpless epoxidation reaction is an enantioselective chemical reaction to prepare 2,3-epoxyalcohols from primary and secondary allylic alcohols....
- explain the selectivity in enantioselective epoxidations with chiral ketones. Diastereoselective epoxidation may be achieved through the use of alkene starting...
- than 10 (pH 10.5) substoichiometric amounts (0.2–0.3) are needed for epoxidations, lowering the decomposition of reagents by disfavoring the Baeyer-Villiger...
- nucleophilic epoxidation is naturally complementary in scope to electrophilic epoxidations such as the Sharpless epoxidation and Jacobsen epoxidation. The stereoinduction...
- Jacobsen epoxidation, sometimes also referred to as Jacobsen-Katsuki epoxidation is a chemical reaction which allows enantioselective epoxidation of unfunctionalized...
- Although the most commonly used asymmetric epoxidation methods (the Sharpless-Katsuki, and Jacobsen epoxidations) rely on the catalytic reactivity of electrophilic...
- Karen; Eickhoff, David J. (1981). "Vanadium-catalyzed epoxidations. 2. Highly stereoselective epoxidations of acyclic homoallylic alcohols predicted by a detailed...
- Involving a Combination of Anomeric and Cieplak Effects in Sulfur Ylide Epoxidations with Chiral 1,3-Oxathianes". Journal of the American Chemical Society...
- chloride reacts preferentially at the disubstituted alkene, whereas epoxidation with mCPBA occurs at the trisubstituted alkene. In another synthetic...