- well as
Delepine (1920)
studied episulfides. I 1934
Dachlauer and
Jackel devised a
general synthesis of
episulfides from
epoxides using alkali thiocyanates...
- PPh3.
Triphenylphosphine abstracts sulfur from
polysulfide compounds,
episulfides, and
elemental sulfur.
Simple organosulfur compounds such as
thiols and...
-
Phosphorus Phosphirane Phosphirene Sulfur Thiirane (ethylene sulfide,
episulfides)
Thiirene Three-membered
rings with two
heteroatoms Heteroatoms Saturated...
- C2H4S. It is the
smallest sulfur-containing
heterocycle and the
simplest episulfide. Like many
organosulfur compounds, this
species has a
highly unpleasant...
-
related reaction, KSCN
converts cyclohexene oxide to the
corresponding episulfide and KOCN. C 6 H 10 O + KSCN ⟶ C 6 H 10 S + KOCN {\displaystyle {\ce {C6H10O...
-
gives the alkene. When
treated with thiourea,
epoxides convert to the
episulfide (thiiranes).
Epoxides undergo ring
expansion reactions,
illustrated by...
- with a three-member ring
structure - such as epoxides, aziridines, and
episulfides -
undergo anionic ROP. A
typical example of
anionic ROP is that of ε-caprolactone...
- it is left open
whether this
latter process occurs at the
stage of the
episulfide. This
reaction concept developed at this stage,
dubbed sulfide contraction...
-
sulfide is
useful for the
conversion of
epoxides to the
corresponding episulfides: Ph2C2H2O + Ph3PS → Ph2C2H2S + Ph3PO It also
reacts with
ketenes to form...
- Methylepitiostanol,
known by the
nicknames Epistane, Hemapolin, Havoc, and Epi Plex, is a
synthetic and
orally active anabolic–androgenic
steroid (AAS)...
